Oplysninger om | engelsk ord INTERSYSTEM

L'Inflexible received TIT (Traitement de l'Information Tactique, "Tactical Information Processor"), a cluster of French-designed computers and serial digital bus links for intersystem communication and DMUX21 sonar.
In order to take advantage of both the thermodynamics and kinetics of the reaction, the industrial scale water gas shift reaction is conducted in multiple adiabatic stages consisting of a high temperature shift (HTS) followed by a low temperature shift (LTS) with intersystem cooling.
It differs from intersystem crossing in that, while both are radiationless methods of de-excitation, the molecular spin state for internal conversion remains the same, whereas it changes for intersystem crossing.
As an alternative a pericyclic reaction mechanism is proposed, in which after intersystem crossing a radical cation and a radical anion are formed, which then recombine to the cyclobutane.
For example, dibromomethane and hexafluorobenzene deactivate the higher-energy singlet state, decelerating the rate of intersystem crossing in accordance with earlier studies of diphenylcarbene.

Sideforberedelse tog: 195,47 ms.

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