Synoniemen & Informatie over | Engels woord SOLVATION

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Voorbeelden van het gebruik van SOLVATION in een zin

• The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile.
• 53A5 - optimised by first fitting to reproduce the thermodynamic properties of pure liquids of a range of small polar molecules and the solvation free enthalpies of amino acid analogs in cyclohexane, is an expansion and renumbering of 45A3.
• Any matter dissolved (or otherwise suspended) in the superfluid will tend to aggregate together in clumps, encapsulated by a 'quantum solvation shell'.
• A solvation shell or solvation sheath is the solvent interface of any chemical compound or biomolecule that constitutes the solute in a solution.
• In thermochemistry, the enthalpy of solution (heat of solution or enthalpy of solvation) is the enthalpy change associated with the dissolution of a substance in a solvent at constant pressure resulting in infinite dilution.
• Oktay Sinanoğlu (February 25, 1935 – April 19, 2015) was a Turkish physical chemist and molecular biophysicist who made significant contributions to the theory of electron correlation in molecules, the statistical mechanics of clathrate hydrates, quantum chemistry, and the theory of solvation.
• One group in Ukraine did an in-depth study on the role of nucleophilic solvation and its effect on the mechanism of bond heterolysis.
• In a solvent environment, SFA can even measure the oscillatory solvation and structural forces arising from the packing of individual layers of solvent molecules.
• Thus, ionic kosmotropes are characterized by strong solvation energy leading to an increase of the overall cohesiveness of the solution, which is also reflected by the increase of the viscosity and density of the solution.
• The calculated energetics of the hydronium solvation shells were reported in 2007 and it was suggested that the activation energies of the two proposed mechanisms do not agree with their calculated hydrogen bond strengths, but mechanism 1 might be the better candidate of the two.
• An important and exploitable property of aurophilic interactions relevant to their supramolecular chemistry is that while both inter- and intramolecular interactions are possible, intermolecular aurophilic linkages are comparatively weak and easily broken by solvation; most complexes that exhibit intramolecular aurophilic interactions retain such moieties in solution.
• A set of solvation parameters derived for protein interior from protein engineering data was also different from octanol scale: it was close to cyclohexane scale for nonpolar atoms but intermediate between cyclohexane and octanol scales for polar atoms.
• The chemical synthesis of large peptides is still limited by problems of low solvation during solid phase peptide synthesis (SPPS) or limited solubility of fully protected peptide fragments: even chemoselective ligation methods are hampered by self-association of unprotected peptide blocks.
• Polarized embedding schemes have scarcely been applied to bio-molecular simulations and have essentially been restricted to explicit solvation models where the solute will be treated as a QM system and the solvent a polarizable force field.
• An important and exploitable property of aurophilic interactions relevant to their supramolecular chemistry is that while both inter- and intramolecular interactions are possible, intermolecular aurophilic linkages are comparatively weak and the gold–gold bonds are easily broken by solvation; most complexes that exhibit intramolecular aurophilic interactions retain such moieties in solution.
• The fluorinated chemical compounds produced by ECF are useful because of their distinctive solvation properties and the relative inertness of carbon–fluorine bonds.
• The thermophoresis of a fluorescently labeled molecule A typically differs significantly from the thermophoresis of a molecule-target complex AT due to size, charge and solvation entropy differences.
• Lithium hexasulfide (which contains , another polysulfide radical anion) with tetramethylenediamine solvation dissociates acetone and related donor solvents to.
• Truhlar is known for his contributions to theoretical chemical dynamics of chemical reactions; quantum mechanical scattering theory of chemical reactions and molecular energy transfer; electron scattering; theoretical kinetics and chemical dynamics; potential energy surfaces and molecular interactions; path integrals; variational transition state theory; the use of electronic structure theory for calculations of chemical structure, reaction rates, electronically nonadiabatic processes, and solvation effects; photochemistry; combustion chemistry; heterogeneous, homogeneous, and enzyme catalysis; atmospheric and environmental chemistry; drug design; nanoparticle structure and energetics; and density functional theory, including the Minnesota Functionals.
• Conway was a "complete" electrochemist in that he worked on nearly all aspects of electrochemistry: the electrified interface, ion solvation, adsorption, electrode kinetics and solvated electron, oxide film formation, electrocatalysis, rechargeable batteries, and electrochemical capacitors.

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